Splitting CO2 into CO and O2 by a single catalyst
Public Deposited- Creator
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Chen, Zuofeng
- University of North Carolina at Chapel Hill
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Concepcion, Javier J.
- University of North Carolina at Chapel Hill
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Brennaman, M. Kyle
- University of North Carolina at Chapel Hill
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Kang, Peng
- University of North Carolina at Chapel Hill
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Norris, Michael R.
- University of North Carolina at Chapel Hill
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Hoertz, Paul G.
- Other Affiliation: RTI International
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Meyer, Thomas J.
- University of North Carolina at Chapel Hill
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Chen, Zuofeng
- Abstract
- The metal complex [(tpy)(Mebim-py)RuII(S)]2+ (tpy = 2,2′ : 6′,2′′-terpyridine; Mebim-py = 3-methyl-1-pyridylbenzimidazol-2-ylidene; S = solvent) is a robust, reactive electrocatalyst toward both water oxidation to oxygen and carbon dioxide reduction to carbon monoxide. Here we describe its use as a single electrocatalyst for CO2 splitting, CO2 → CO + 1/2 O2, in a two-compartment electrochemical cell.
- Date of publication
- 2012
- Keyword
- DOI
- Identifier
- Publisher DOI: https://doi.org/10.1073/pnas.1203122109
- PMCID: PMC3465442
- PMID: 22685210
- Onescience id: c6418d56607cd3243f704b6e4079744a301a7279
- Resource type
- Article
- Rights statement
- In Copyright
- Journal title
- Proceedings of the National Academy of Sciences of the United States of America
- Journal volume
- 109
- Journal issue
- 39
- Page start
- 15606
- Page end
- 15611
- Language
- English
- ISSN
- 1091-6490
- 0744-2831
- 0027-8424
Relations
- Parents:
This work has no parents.
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