Synthesis and complexation of bis(imino)aryl ligands: towards the generation of iridium based water oxidation catalysts Public Deposited

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Alternate title
  • Synthesis and complexation of bisiminoaryl ligands
Last Modified
  • March 21, 2019
Creator
  • Finniss, Mathew C.
    • Affiliation: College of Arts and Sciences, Department of Chemistry
Abstract
  • The C,C-trans bis-cyclometalation of 2,6-diphenylpyridine across an iridium center was investigated. Equally the synthesis and complexation of a series of bis(imino)aryl ligands was studied. Installing methyl and fluoro substituents in the backbone of the ligand prevented the C-H activation of the 4- and 6- positions and resulted in metalation of the 2- position...
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  • In Copyright
Note
  • "... in partial fulfillment of the requirements for the degree of Master of Arts in the Department of Chemistry."
Advisor
  • Templeton, Joseph
Degree granting institution
  • University of North Carolina at Chapel Hill
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Place of publication
  • Chapel Hill, NC
Access
  • Open access
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