Approaches to Hydrocarbon Functionalization Using Heteroatom-Centered Radicals Public Deposited

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Last Modified
  • March 19, 2019
Creator
  • Quinn, Ryan
    • Affiliation: College of Arts and Sciences, Department of Chemistry
Abstract
  • This dissertation covers the development of a class of organic transformations. The first of these involve the development of amidyl radicals for the functionalization of unactivated aliphatic C-H bonds. C-H Bromination and Chlorination methods are reported, as well as their synthetic application toward synthesis. Recent efforts toward catalytic variants of similar transformations are also reported. Lastly, this dissertation focuses on the development of amidoxyl radicals used for alkene difunctionalizations,more specifically carbooxygenation reactions.
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Rights statement
  • In Copyright
Advisor
  • Gagne, Michel
  • Johnson, Jeffrey
  • Meek, Simon
  • Aubé, Jeffrey
  • Alexanian, Erik
Degree
  • Doctor of Philosophy
Degree granting institution
  • University of North Carolina at Chapel Hill Graduate School
Graduation year
  • 2016
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