NICKEL-CATALYZED CYCLOADDITIONS OF ENE-ALLENES Public Deposited

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  • March 19, 2019
Creator
  • Noucti, Njamkou
    • Affiliation: College of Arts and Sciences, Department of Chemistry
Abstract
  • Nickel–catalyzed reactions of alkene and allene π–components are reported. Through ligand–controlled selectivity, a common intermediate can be diverted to four distinct reaction pathways: (1) [2+2+2] cycloaddition reactions, (2) alkenylative cyclization reactions, (3) [2+2] cycloaddition reactions, and (4) cycloisomerization reactions. The reactions utilize an inexpensive and commercially–available Ni–catalyst system with a diverse array of alkene and allene π–components to efficiently deliver stereochemically dense cycloalkanes.
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  • In Copyright
Advisor
  • Meek, Simon
  • Johnson, Jeffrey
  • Alexanian, Erik
  • Brookhart, Maurice
  • Waters, Marcey
Degree
  • Doctor of Philosophy
Degree granting institution
  • University of North Carolina at Chapel Hill Graduate School
Graduation year
  • 2015
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  • Chapel Hill, NC
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