NICKEL-CATALYZED CYCLOADDITIONS OF ENE-ALLENES Public Deposited
- Last Modified
- March 19, 2019
- Creator
-
Noucti, Njamkou
- Affiliation: College of Arts and Sciences, Department of Chemistry
- Abstract
- Nickel–catalyzed reactions of alkene and allene π–components are reported. Through ligand–controlled selectivity, a common intermediate can be diverted to four distinct reaction pathways: (1) [2+2+2] cycloaddition reactions, (2) alkenylative cyclization reactions, (3) [2+2] cycloaddition reactions, and (4) cycloisomerization reactions. The reactions utilize an inexpensive and commercially–available Ni–catalyst system with a diverse array of alkene and allene π–components to efficiently deliver stereochemically dense cycloalkanes.
- Date of publication
- May 2015
- Keyword
- Subject
- DOI
- Identifier
- Resource type
- Rights statement
- In Copyright
- Advisor
- Waters, Marcey
- Brookhart, Maurice
- Meek, Simon
- Johnson, Jeffrey
- Alexanian, Erik
- Degree
- Doctor of Philosophy
- Degree granting institution
- University of North Carolina at Chapel Hill Graduate School
- Graduation year
- 2015
- Language
- Publisher
- Place of publication
- Chapel Hill, NC
- Access
- There are no restrictions to this item.
- Parents:
This work has no parents.
Items
Thumbnail | Title | Date Uploaded | Visibility | Actions |
---|---|---|---|---|
|
Noucti_unc_0153D_15207.pdf | 2019-04-09 | Public |
|